unusual reactivity patterns of 1,3,6,8-tetraazatricyclo-[4.4.1.13,8]-dodecane (tatd) towards some reducing agents: synthesis of tmeda
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ID: 241521
2007
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Abstract
N,N,N ÃŒÂ,N ÃŒÂ-Tetramethylethylenediamine (TMEDA) can be synthesized by simple reduction of 1,3,6,8-tetraazatricyclo-[4.4.1.1.3,8]dodecane (TATD), an aminal cage type amine, with formic acid. The aminal can be converted to TMEDA in high yield very easily and in a very short time. We comment on the scope and limitations of the reduction of thisaminal and propose a possible reaction mechanism.
| Reference Key |
rios-motta2007moleculesunusual
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|---|---|
| Authors | ;Jaime Rios-Motta;Augusto Rivera |
| Journal | Journal of ethnopharmacology |
| Year | 2007 |
| DOI |
10.3390/12071471
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| URL | |
| Keywords | Keywords not found |
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