Exciplex System with Increased Donor-Acceptor Distance as the Sensitizing Host for Conventional Fluorescent OLEDs with High Efficiency and Extremely Low Roll-Off.

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ID: 2394
2019
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Abstract
Exciplex systems with efficient thermally activated delayed fluorescence as the sensitizing hosts for fluorescent organic light-emitting diodes (OLEDs) have been flourished recently, while the device performances are still lagging behind. Here, a donor molecule sterically encapsulated with tert-butyl units is designed and synthesized to increase the donor-acceptor separation in an exciplex system, leading to reduced singlet-triplet energy gap (Δ Es) and improved reverse intersystem crossing (RISC) efficiency. OLEDs utilizing exciplexes with increased donor-acceptor distance ( r) as the hosts for conventional fluorescent dopants exhibit a maximum external quantum efficiency (EQE) as high as 16.5%, benefiting from the enhanced RISC process and suppressed exciton loss by the Dexter interaction. Furthermore, extremely low efficiency roll-off is obtained with EQEs of 16.2% at 5000 cd/m and 15.2% at 10 000 cd/m. The results here represent the state-of-the-art performances for devices based on exciplexes as the hosts for conventional fluorescent dopants, manifesting the superiority of exciplexes with increased r as the sensitizing hosts for fluorescent dopants.
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song2019exciplexacs Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Song, Xiaozeng;Zhang, Dongdong;Li, Haoyuan;Cai, Minghan;Huang, Tianyu;Duan, Lian;
Journal ACS applied materials & interfaces
Year 2019
DOI
10.1021/acsami.9b05963
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