Doping of Tetraalkylammonium Salts in Polyethylenimine Ethoxylated for Efficient Electron Injection Layers in Solution-Processed Organic Light-Emitting Devices.

Clicks: 317
ID: 2386
2019
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This article has not been analysed, so there is no overall score — reader engagement is measured and shown alongside.
AI Quality Assessment
Not analyzed
Readership in this journal
Emerging

Ranked #119 of 899 articles by views in ACS applied materials & interfaces

Most read Least read

Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 899 in total.

Mint this article as an NFT
Not yet minted

Create a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.

5 SUSD one-off · no wallet required
Sign in to mint
Abstract
For efficient electron injection, a method to control the work functions (WFs) of ZnO electrodes in organic light-emitting devices (OLEDs) is reported in this study. First, ZnO was modified by doping of tetraalkylammonium salts (TRAX) into polyethylenimine ethoxylated (PEIE) for the WF control. Tetrabutylammonium salts (TBAX), where X = chloride, bromide, iodide, acetate, thiocyanate, and tetrafluoroborate anions, were doped into PEIE. A WF of nondoped PEIE-modified ZnO was 3.65 eV, whereas TBAX-doped PEIE-modified ZnO exhibited WFs ranging from 3.52 to 3.00 eV depending on the anion. TBAX salts exhibited different electron-donating capabilities depending on the anion, and the doping of TBAX with a large electron-donating capability exhibited a large WF reduction effect. In addition, tetraethyl- and tetrahexylammonium chlorides were doped into PEIE. PEIE doped with TRACl containing long alkyl chains exhibited a large WF reduction effect due to its low electron-accepting capabilities. In addition, the WF reduction mechanism was considered by the depth direction analysis of the PEIE:TBAX films. Finally, the ZnO/PEIE:TRAX bilayers were applied as electron injection layers in poly[2-methoxy-5-(2-ethylhexyloxy)-1,4-phenylenevinylene] emissive-layer-based OLEDs with an inverted structure. The ZnO/PEIE:TBAX devices with low WFs exhibited low driving voltages.
Reference Key
ohisa2019dopingacs Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Ohisa, Satoru;Suzuki, Michinori;Chiba, Takayuki;Kido, Junji;
Journal ACS applied materials & interfaces
Year 2019
DOI
10.1021/acsami.9b06895
URL
Keywords Keywords not found

Citations

No citations found. To add a citation, contact the admin at info@scimatic.org

Comments

No comments yet. Be the first to comment on this article.