one-pot conversion of epoxidized soybean oil (eso) into soy-based polyurethanes by mocl2o2 catalysis
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2017
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Abstract
An innovative and eco-friendly one-pot synthesis of bio-based polyurethanes is proposed via the epoxy-ring opening of epoxidized soybean oil (ESO) with methanol, followed by the reaction of methoxy bio-polyols intermediates with 2,6-tolyl-diisocyanate (TDI). Both synthetic steps, methanolysis and polyurethane linkage formation, are promoted by a unique catalyst, molybdenum(VI) dichloride dioxide (MoCl2O2), which makes this procedure an efficient, cost-effective, and environmentally safer method amenable to industrial scale-up.
| Reference Key |
pantone2017moleculesone-pot
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|---|---|
| Authors | ;Vincenzo Pantone;Cosimo Annese;Caterina Fusco;Paola Fini;Angelo Nacci;Antonella Russo;Lucia D’Accolti |
| Journal | Journal of ethnopharmacology |
| Year | 2017 |
| DOI |
10.3390/molecules22020333
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| URL | |
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