synthesis and characterization of a gel-type electrolyte with ionic liquid added for dye-sensitized solar cells
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ID: 236105
2013
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Abstract
This study intends to develop the electrolyte needed in dye-sensitized solar cells (DSSCs). Moreover, three different ionic liquids in different molalities are added to the gel-type electrolyte. Experimental results show that the DSSC composed of the gel-type electrolyte with no ionic liquid added can acquire 4.13% photoelectric conversion efficiency. However, the DSSC composed of the gel-type electrolyte with 0.4 M of 1-butyl-3-methylimidazolium chloride added has an open-circuit voltage of 810 mV, a short-circuit current density of 9.56 mA/cm2, and photoelectric conversion efficiency reaching 4.89%. Comparing this DSSC with the DSSC with no ionic liquid added, the photoelectric conversion efficiency can be enhanced by 18.4%. As to durability, the DSSC composed of the gel-type electrolyte with ionic liquid added still has a photoelectric conversion efficiency of 3.28% on the 7th day after it is stored in an enclosed space and maintains 0.72% efficiency on the 14th day. When the proposed DSSC is compared with the DSSC prepared by using a liquid-type electrolyte, the durability of its photoelectric conversion efficiency can be increased by 7 times.
| Reference Key |
shi2013internationalsynthesis
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|---|---|
| Authors | ;Le-Yan Shi;Tien-Li Chen;Chih-Hao Chen;Kun-Ching Cho |
| Journal | construction and building materials |
| Year | 2013 |
| DOI |
10.1155/2013/834184
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| URL | |
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