an experimental and quantumchemical study of [2+3] cycloaddition between (z)-c-(m,m,p-trimethoxyphenyl)-n-(p-methyphenyl)-nitrone and (e)-3,3,3-trichloro-1-nitroprop-1-ene: mechanistic aspects
Clicks: 241
ID: 231021
2015
Article Quality & Performance Metrics
Overall Quality
Improving Quality
0.0
/100
Combines engagement data with AI-assessed academic quality
Reader Engagement
Emerging Content
6.3
/100
21 views
21 readers
Trending
AI Quality Assessment
Not analyzed
Abstract
Analysis of addent interactions with respect to the theory of electrophilicity and nucleophilicity indexes and kinetic studies shows the polar nature of [2+3] cycloaddition of (Z)-C-(m,m,p-trimethoxyphenyl)-N-(p-methylphenyl)-nitrone to (E)-3,3,3-trichloro-1-nitroprop-1-ene. However, PES exploration results do not confirm any zwitterion on the reaction paths. On the other hand, the nature of the solvent effect and the experimentally determined activation parameter values do not exclude a scenario in which one-step and stepwise processes occur simultaneously.
| Reference Key |
szczepanek2015currentan
Use this key to autocite in the manuscript while using
SciMatic Manuscript Manager or Thesis Manager
|
|---|---|
| Authors | ;Alicja Szczepanek;Ewa Jasińska;Agnieszka Kącka,;Radomir Jasiński |
| Journal | proceedings - 2018 4th international conference on computing, engineering, and design, icced 2018 |
| Year | 2015 |
| DOI |
10.5267/j.ccl.2014.10.003
|
| URL | |
| Keywords |
Citations
No citations found. To add a citation, contact the admin at info@scimatic.org
Comments
No comments yet. Be the first to comment on this article.