relative and absolute stereochemistry of diacarperoxides: antimalarial norditerpene endoperoxides from marine sponge diacarnus megaspinorhabdosa
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ID: 228841
2014
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Abstract
Five new norditerpene endoperoxides, named diacarperoxides H–L (1–5), and a new norditerpene diol, called diacardiol B (6), were isolated from the South China Sea sponge, Diacarnus megaspinorhabdosa. Their structures, including conformations and absolute configurations, were determined by using spectroscopic analyses, computational approaches and chemical degradation. Diacarperoxides H–J (1–3) showed some interesting stereochemical issues, as well as antimalarial activity.
| Reference Key |
yang2014marinerelative
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| Authors | ;Fan Yang;Yike Zou;Ru-Ping Wang;Mark T. Hamann;Hong-Jun Zhang;Wei-Hua Jiao;Bing-Nan Han;Shao-Jiang Song;Hou-Wen Lin |
| Journal | jixie gongcheng xuebao/journal of mechanical engineering |
| Year | 2014 |
| DOI |
10.3390/md12084399
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