chlorine anion encapsulation by molecular capsules based on cucurbit[5]uril and decamethylcucurbit[5]uril
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ID: 228425
2007
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Abstract
Three barrel-shaped artificial molecular capsules 1-3, based on normal cucurbit[5]uril (Q[5]) and decamethylcucurbit[5]uril (Me10Q[5]), were synthesized and structurally characterized by single-crystal X-ray diffraction. Encapsulation of a chlorine anion in the cavity of a Q[5] or Me10Q[5] to form closed a molecular capsule with the coordinated metal ions or coordinated metal ions and water molecules in the crystal structures of these compounds is common. The three complexes [Pr2(C30H30N20O10)Cl3(H2O)13]3+3Cl-·5H2O (1), [Sr2(C40H50N20O10)(H2O)4Cl]3+3Cl-·2(HCl) 19H2O (2) and [K(C40H50N20O10)(H2O)Cl]·[Zn(H2O)2Cl2]·[ZnCl4]2-·2(H3O)+·8H2O (3) all crystallize as isolated molecular capsules.
| Reference Key |
tao2007moleculeschlorine
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|---|---|
| Authors | ;Zhu Tao;Sai-Feng Xue;Qian-Jiang Zhu;Yun-Qian Zhang |
| Journal | Journal of ethnopharmacology |
| Year | 2007 |
| DOI |
10.3390/12071325
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| URL | |
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