Synthesis, structure and magnetic properties of copper(ii) azide.
Clicks: 249
ID: 2270
2019
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Abstract
A novel azide-bridged copper compound without an auxiliary ligand has been synthesized and characterized by single-crystal diffraction analysis. The compound consists of 1D double chains with end-on (EO) azide bridges. Furthermore, the neighboring chains are connected by weak coordination bonds, which leads to the formation of a 3D architecture. Low-temperature magnetic measurements reveal that antiferromagnetic interactions are dominant, with concomitant spin-canted antiferromagnetism.
| Reference Key |
shi2019synthesisdalton
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| Authors | Shi, Taqing;Xu, Ye;Zou, Ya-Jing;Wang, Zhao-Xi; |
| Journal | Dalton transactions (Cambridge, England : 2003) |
| Year | 2019 |
| DOI |
10.1039/c9dt01450k
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| URL | |
| Keywords | Keywords not found |
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