Redox-Guest Induced Multi-mode Photoluminescence Switch for Sequential Logic Gates in a Photoactive Coordination Cage.

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ID: 2269
2019
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Abstract
Photoluminescence (PL) modulation in molecular or supramolecular level can provide potentials for high density data processing by combining chemical and photonic input/output signals together in a nanoscale integrated system. Herein, a PL-responsive supramolecular coordination cage has been applied for interactions with redox-active guests. PL signals of the cage can be switched and modulated by adding/retracting Fc derivatives or converting TTF into different oxidation states via chemical or photochemical pathways. As a result, reversible or stepwise PL switches are displayed by these host-guest systems due to occurrence of PET (photoinduced electron-transfer) or FREnT (fluorescence resonance energy transfer) processes, providing nano-device models for off/on logic gate or memristor-like sequential Boolean operation functions.
Reference Key
hou2019redoxguestchemistry Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Hou, Ya-Jun;Wu, Kai;Lu, Yu-Lin;Fan, Yan-Zhong;Fan, Ya-Nan;Yu, Hui-Juan;Li, Kang;Pan, Mei;Su, Cheng-Yong;
Journal Chemistry (Weinheim an der Bergstrasse, Germany)
Year 2019
DOI
10.1002/chem.201901612
URL
Keywords Keywords not found

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