the composition-tunable polydiacetylenic complex films: conformational change upon thermal stimulation and preferential interaction with specific small molecules

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ID: 223998
2017
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Abstract
Polydiacetylenic complex films were prepared using 10,12-pentacosadiynoic acid (PCDA) and para-xylenediamine (pXDA) upon acid-base interactions. The thermochromatic reversibility of the complex films was modulated by changing the mixed molar ratio (3 : 1, 2 : 1, and 1 : 1) of the two molecules. The corresponding conformational changes of the complex films were studied by ex situ FTIR analysis upon thermal stimulation for the first time. In addition, the binding specificities of α-, β-, and γ-cyclodextrins (CDs) with the films were studied, where the α-CDs can induce stronger red fluorescent emission of the films. These fundamental results may be useful for platforms that use these polydiacetylenic complex films as optoelectronic devices or chemical/biological sensors.
Reference Key
wang2017journalthe Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Chao Wang;Jin Hyuk Park;Songwen Tan;Chunzhi Cui;Jing-Yi Jin;Dong June Ahn
Journal reproductive biology and endocrinology
Year 2017
DOI
10.1155/2017/5983106
URL
http://dx.doi.org/10.1155/2017/5983106
Keywords
Technology (General) ophthalmology gait analysis arthritis pi3k computer engineering pharmacology clinical endocrinology information resources diseases of the endocrine glands library science computer hardware flow experiencebibliography

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