ldpe oxidation by co2 laser radiation (10.6 µm)
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ID: 223468
2018
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Abstract
Thermooxidation of LDPE films by CO2 laser radiation, 10.6 μm, was characterized by Fourier transform infrared spectroscopy with attenuated total reflectance (FTIR-ATR). The formation of carbonyl and hydroxyl functional groups onto LDPE films was dependent on the fluency of CO2 laser. IR absorption of vinyl groups and C-O bond present in alcohols showed a decrease and an increase, respectively, indicating that CO2 laser radiation causes simultaneous formation and accumulation of hydroperoxides in LDPE films; furthermore, crystallinity of LDPE films irradiated with CO2 tends to increase. So, CO2 laser radiation is able to oxidize the LDPE films, obtaining a PE with similar spectroscopic properties to that of PE-BIO by a physical process.
| Reference Key |
martnez-romo2018internationalldpe
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|---|---|
| Authors | ;A. Martínez-Romo;R. González-Mota;J. J. Soto-Bernal;I. Rosales-Candelas |
| Journal | 19th international congress of chemical and process engineering, chisa 2010 and 7th european congress of chemical engineering, ecce-7 |
| Year | 2018 |
| DOI |
10.1155/2018/5150673
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