offer a novel method for size appraise of nio nanoparticles by pl analysis: synthesis by sonochemical method
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2016
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Abstract
In this work, we will discuss the optical properties of NiO nanoparticles that we have investigated recently by photoluminescence (PL) spectroscopy. In particular, we will show the blue-shifts of PL, originating from the electron–hole recombination of the self-trapped exciton (STE), observed in smaller-sized NiO nanoparticles. To explain the size effect in relating to the STE PL shift, a question has been raised on whether it is appropriate to apply him quantum confinement (QC) theory usually used for the Mott-Winner type excitons in semiconductors to wide band-gap material, such as silica. Variations in several parameters and their effects on the structural (crystal size and morphology) properties of nanoparticles were investigated. Characterizations were carried out by X-ray diffraction (XRD), scanning electron microscopy (SEM), thermal stability (TGA and DTA), solid state UV and solid state florescent (PL).
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| Authors | ;Seyid Javad Musevi;Alireza Aslani;Hamid Motahari;Hassan Salimi |
| Journal | zaporožskij medicinskij Žurnal |
| Year | 2016 |
| DOI |
10.1016/j.jscs.2012.06.009
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