ir, 1h-nmr, uv-vis and thermal studies on the rhodamine 6g charge-transfer complexes

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ID: 217251
2011
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Abstract
Charge-transfer (CT) complexes formed between Rhodamine 6G (Rh6G) as donor with iodine, CLA and PA as acceptors have been studied spectrophotometrically. The synthesis and characterization of Rhodamine 6G CT-complexes of iodine, [(Rh6G)2]I+.I3ˉ, chloranilic acid (CLA), [(Rh6G)(CLA)] and picric acid (PA) [(Rh6G)(PA)] were described. These complexes are readily prepared from the reaction of Rh6G with I2, CLA and PA with CHCl3 solvent. Mid and far IR, 1H-NMR, UV-Vis techniques, elemental analyses (CHN) and thermal studies, characterize the three new Rhodamine 6G charge-transfer complexes. Modified Benesi-Hildebrand method was applied to the determination of association constant and molar extinction coefficient.
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Authors ;Moamen S. Refat;Hamada M.A. Killa;M.Y. El-Sayed
Journal Experimental physiology
Year 2011
DOI
DOI not found
URL
http://ajol.info/index.php/bcse/article/view/63377
Keywords
iodine picric acid

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