synthesis and structural characterization of a zn(ii) coordination polymer based on 4,4’-bipyridine and acetato

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ID: 217120
2015
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Abstract
A novel Zn(II) coordination polymer, [Zn(bpy)(acetato)2]n (bpy = 4,4’-bipyridine), has been synthesized and characterized by elemental analysis and single-crystal X-ray diffraction. The Zn(II) coordination polymer is triclinic, space group P-1 with a = 8.046(3) Å, b = 9.161(3) Å, c = 10.663(3) Å, α = 109.769(4)º, β = 99.966(5)º, γ = 101.666(5)º, V= 699.1(4) Å3, Z = 2, Dc = 1.614 mg·m-3, μ = 1.774 mm-1, F(000) = 348, and final R1 = 0.0541, ωR2 = 0.1605. X-ray diffraction analysis reveals that the Zn(II) center is six-coordination with a N2O4 distorted octahedral coordination environment. The Zn(II) complex forms 1D chain structure by the bridge of 4,4’-bipyridine and acetato.
Ein neuartiges Zn(II)-Koordinationspolymer, [Zn(bpy)(acetato)2]n (bpy = 4,4’-Bipyridin), wurde synthetisiert und mittels Elementaranalyse sowie Einkristall-Röntgenbeugung charakterisiert. Das Zn(II)-Koordinationspolymer ist triklin, Raumgruppe P-1 mit a = 8,046(3) Å, b = 9,161(3) Å, c = 10,663(3) Å, α = 109,769(4)º, β = 99,966(5)º, γ = 101,666(5)º, V= 699,1(4) Å3, Z = 2, Dc = 1,614 mg·m-3, μ = 1,774 mm-1, F(000) = 348 und finalem R1 = 0,0541, ωR2 = 0,1605. Die Röntgenbeugungsanalyse zeigt, dass das Zn(II)-Zentrum sechsfach koordiniert vorliegt und eine verzerrt-oktaedrische N2O4-Koordinationsumgebung aufweist. Der Zn(II)-Komplex bildet über die Verbrückung durch 4,4’-Bipyridin und Acetat eine 1D-Kettenstruktur aus.
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Authors Li-Hua Wang
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Journal Mineralogical Magazine
Year 2015
DOI
DOI not found
URL
http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201501&vol=1&aid=4207
Keywords
synthesis

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