[(1,2,5,6-η)-cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene-κc2)(triphenylphosphane-κp)iridium(i) tetrafluoridoborate

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ID: 215461
2017
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Abstract
In the title compound, [Ir(C8H12)(C8H14N2)(C18H15P)]BF4, the cationic complex has the anticipated square-planar geometry. The asymmetric unit comprises the iridium complex and one tetrafluoridoborate anion. The space group is non-centrosymmetric, with the Flack parameter of 0.007 (3) well determined, and confirms the hand for the complex cation. This compound shows promising catalytic activity in transfer hydrogenation reactions.
Reference Key
idrees2017iucrdata[(1,2,5,6-)-cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene-c2)(triphenylphosphane-p)iridium(i) Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Karam B. Idrees;William J. Rutledge;Sue A. Roberts;Edward Rajaseelan
Journal lecture notes in civil engineering
Year 2017
DOI
10.1107/S2414314617014110
URL
http://scripts.iucr.org/cgi-bin/paper?S2414314617014110
Keywords
Imidazole crystal structure 5-dienecrystallography

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