[(1,2,5,6-η)-cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene-κc2)(triphenylphosphane-κp)iridium(i) tetrafluoridoborate
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2017
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Abstract
In the title compound, [Ir(C8H12)(C8H14N2)(C18H15P)]BF4, the cationic complex has the anticipated square-planar geometry. The asymmetric unit comprises the iridium complex and one tetrafluoridoborate anion. The space group is non-centrosymmetric, with the Flack parameter of 0.007 (3) well determined, and confirms the hand for the complex cation. This compound shows promising catalytic activity in transfer hydrogenation reactions.
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idrees2017iucrdata[(1,2,5,6-)-cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene-c2)(triphenylphosphane-p)iridium(i)
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| Authors | ;Karam B. Idrees;William J. Rutledge;Sue A. Roberts;Edward Rajaseelan |
| Journal | lecture notes in civil engineering |
| Year | 2017 |
| DOI |
10.1107/S2414314617014110
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| URL | |
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