thermodynamic study of tl6sbr4 compound and some regularities in thermodynamic properties of thallium chalcohalides
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ID: 214559
2017
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Abstract
The solid-phase diagram of the Tl-TlBr-S system was clarified and the fundamental thermodynamic properties of Tl6SBr4 compound were studied on the basis of electromotive force (EMF) measurements of concentration cells relative to a thallium electrode. The EMF results were used to calculate the relative partial thermodynamic functions of thallium in alloys and the standard integral thermodynamic functions (-ΔfG0, -ΔfH0, and S0298) of Tl6SBr4 compound. All data regarding thermodynamic properties of thallium chalcogen-halides are generalized and comparatively analyzed. Consequently, certain regularities between thermodynamic functions of thallium chalcogen-halides and their binary constituents as well as degree of ionization (DI) of chemical bonding were revealed.
| Reference Key |
babanly2017advancesthermodynamic
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| Authors | ;Dunya Mahammad Babanly;Qorkhmaz Mansur Huseynov;Ziya Saxaveddin Aliev;Dilgam Babir Tagiyev;Mahammad Baba Babanly |
| Journal | bulletin of the korean chemical society |
| Year | 2017 |
| DOI |
10.1155/2017/5370289
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