photon conversion and radiation synergism in eu/tb complexes incorporated poly methyl methacrylate

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ID: 214255
2016
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Abstract
Green and red emissions in terbium and europium benzoic acids (TBA and EBA) incorporated poly methyl methacrylates (PMMA) are exhibited. Larger intensity parameters Ω2 (11.13×10-20 cm2) and Ω4 (13.15×10-20 cm2) of Eu3+ indicate a high inversion asymmetrical and strong covalent environment around lanthanide (Ln) ions and maximum emission cross section σem-max (2.45×10-21 cm2) for the dominant transition D50→F27 of Eu3+ reveals the effective photon conversion capacity in EBA incorporated PMMA. Color variation and fluorescence enhancement are validated to be originated from energy transfer and synergistic effect in TBA/EBA coincorporated PMMA system. The results indicate that Eu and Tb complexes incorporated PMMA with effective photon conversion hold great prospect in increment of lighting quality and enhancement of solar-cell efficiency employed in outer space.
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xiao2016advancesphoton Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors P. Xiao, J. J. Zhang, Z. Q. Wang, H. Lin
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Journal bulletin of the korean chemical society
Year 2016
DOI
10.1155/2016/2618253
URL
http://dx.doi.org/10.1155/2016/2618253
Keywords
materials of engineering and construction mechanics of materials

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