iminoiodane- and brønsted base-mediated cross dehydrogenative coupling of cyclic ethers with 1,3-dicarbonyl compounds
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ID: 213772
2015
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Abstract
A one-pot, two-step approach to prepare 2-tetrahydrofuran and -pyran substituted 1,3-dicarbonyl compounds by PhI=NTs-mediated amination/Brønsted base-catalyzed cross dehydrogenative coupling (CDC) reaction of the cyclic ether and 1,3-dicarbonyl derivative under mild conditions is reported. The reaction is compatible with a variety of cyclic ethers and 1,3-dicarbonyl compounds, affording the corresponding coupled products in moderate to good yields of up to 80% over two steps.
| Reference Key |
tejo2015moleculesiminoiodane-
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|---|---|
| Authors | ;Ciputra Tejo;Xiao Rong Sim;Bo Ra Lee;Benjamin James Ayers;Chung-Hang Leung;Dik-Lung Ma;Philip Wai Hong Chan |
| Journal | Journal of ethnopharmacology |
| Year | 2015 |
| DOI |
10.3390/molecules200713336
|
| URL | |
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