aspectos da hidratação de óxido de magnésio em formulações de concretos refratários aspects of magnesium oxide hydration in refractory castables compositions
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2006
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Abstract
Óxido de magnésio (MgO) ou magnésia é uma das matérias primas mais importantes para a indústria de refratários. Graças à sua elevada refratariedade (ponto de fusão da ordem de 2800 ºC) e resistência à corrosão me meios básicos, associadas a custos relativamente baixos, sua utilização em tijolos permitiu um significativo aumento no desempenho e durabilidade desses materiais. No entanto, como uma seqüência natural da utilização desse material, seu uso em concretos refratários não obteve o mesmo impacto em aplicações industriais devido à sua elevada tendência em reagir com água e a decorrente expansão volumétrica gerada. Desse modo, adições de magnésia em concretos têm sido restritas a baixos teores (> 10% peso) e ao uso de partículas grosseiras (> 100 µm). Neste trabalho, foram analisados criteriosamente os diversos estudos referentes à hidratação do MgO em concretos refratários, o impacto gerado nas diferentes etapas de processamento desses materiais e as técnicas empregadas para evitá-la.
Magnesium oxide (MgO) or magnesia is one of the most important raw materials for the refractories industry. Because of high refractoriness (melting point of 2800 ºC), corrosion resistance in basic environments and relatively low costs, its use in bricks has allowed a significant increase in the performance and service life of these materials. However, its use in refractory castables did not attain the same impact in industrial applications because of its great tendency in react with water and the consequent volumetric expansion generated. Therefore, magnesia additions in castables has been kept in small amounts (bellow 10 wt%) and restricted to large particles (> 100 µm). In the present work, several reports on magnesia hydration in refractory castables, its effects on the castables processing and the anti-hydration techniques were critically reviewed.
Magnesium oxide (MgO) or magnesia is one of the most important raw materials for the refractories industry. Because of high refractoriness (melting point of 2800 ºC), corrosion resistance in basic environments and relatively low costs, its use in bricks has allowed a significant increase in the performance and service life of these materials. However, its use in refractory castables did not attain the same impact in industrial applications because of its great tendency in react with water and the consequent volumetric expansion generated. Therefore, magnesia additions in castables has been kept in small amounts (bellow 10 wt%) and restricted to large particles (> 100 µm). In the present work, several reports on magnesia hydration in refractory castables, its effects on the castables processing and the anti-hydration techniques were critically reviewed.
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| Authors | ;R. Salomão;L. R. M. Bittencourt;V. C. Pandolfelli |
| Journal | Zootaxa |
| Year | 2006 |
| DOI |
10.1590/S0366-69132006000200005
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