controlled bulk properties of composite polymeric solutions for extensive structural order of honeycomb polysulfone membranes

Clicks: 148
ID: 210455
2016
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Ranked #39 of 40 articles by views in advances in pharmacological sciences

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Abstract
This work provides additional insights into the identification of operating conditions necessary to overcome a current limitation to the scale-up of the breath figure method, which is regarded as an outstanding manufacturing approach for structurally ordered porous films. The major restriction concerns, indeed, uncontrolled touching droplets at the boundary. Herein, the bulk of polymeric solutions are properly managed to generate honeycomb membranes with a long-range structurally ordered texture. Water uptake and dynamics are explored as chemical environments are changed with the intent to modify the hydrophilic/hydrophobic balance and local water floatation. In this context, a model surfactant such as the polyoxyethylene sorbitan monolaurate is used in combination with alcohols at different chain length extents and a traditional polymer such as the polyethersufone. Changes in the interfacial tension and kinematic viscosity taking place in the bulk of composite solutions are explored and examined in relation to competitive droplet nucleation and growth rate. As a result, extensive structurally ordered honeycomb textures are obtained with the rising content of the surfactant while a broad range of well-sized pores is targeted as a function of the hydrophilic-hydrophobic balance and viscosity of the composite polymeric mixture. The experimental findings confirm the consistency of the approach and are expected to give propulsion to the commercially production of breath figures films shortly.
Reference Key
gugliuzza2016membranescontrolled Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Annarosa Gugliuzza;Maria Luisa Perrotta;Enrico Drioli
Journal advances in pharmacological sciences
Year 2016
DOI
10.3390/membranes6020027
URL
http://www.mdpi.com/2077-0375/6/2/27
Keywords Keywords not found

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