reações de oxidação de derivados de cis-octalinas promovidas por trinitrato de tálio (ttn) oxidation reactions of derivatives of cis-octalins promoted by thallium trinitrate (ttn)

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ID: 210131
2008
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Abstract
The reaction of ten cis-octalins and cis-octalones with thallium trinitrate (TTN) leads to different products, depending mainly on the substitution pattern of the substrate. Functionalized cis-hydrindanes were obtained from the reaction of 1,2,3,4,4a,5,8,8a-octahydro-4a-methylnaphthalene and of 1,2,3,4,4a,5,8,8a-octahydro-4a,7-dimethylnaphthalene with TTN in acetonitrile, whereas a cyclic ether was formed treating 1,2,3,4,4a,5,8,8a-octahydro-6,8a-dimethylnaphthalen-1-ol with TTN in trimethylorthoformate (TMOF).
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Authors ;Helena M. C. Ferraz;Vânia M. T. Carneiro;Tiago O. Vieira;Luiz F. Silva Jr.
Journal greece and rome
Year 2008
DOI
10.1590/S0100-40422008000400014
URL
http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000400014
Keywords
octalinchemistry

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