synthesis and rearrangement of 3-methyl-1,4-pentadiyne-3-ol
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ID: 209658
2002
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Abstract
An efficient synthesis and rearrangement of 3-methyl-1,4-pentadiyne-3-ol (1) using perrhenate- and Mo(VI)-catalysts is reported. The by-products 3,6-dimethyl-1,4,7-octatriyne-3,6-diol (2) and 3-ethynyl-5-methyl-1,6-heptadiyne-3,5-diol (3) were isolated and spectroscopically characterized. A possible reaction mechanism for the formation of the byproducts is discussed.
| Reference Key |
bonrath2002moleculessynthesis
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|---|---|
| Authors | ;Werner Bonrath;Andreas Thum;Horst Pauling;Dominik Buser |
| Journal | Journal of ethnopharmacology |
| Year | 2002 |
| DOI |
10.3390/70300341
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| URL | |
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