a new perspective on classical ideal gases

Clicks: 70
ID: 205876
2013
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Ranked #382 of 406 articles by views in European journal of medicinal chemistry

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Abstract
The ideal-gas barometric and pressure laws are derived from the Democritian concept of independent corpuscles moving in vacuum, plus a principle of simplicity, namely that these laws are independent of the kinetic part of the Hamiltonian. A single corpuscle in contact with a heat bath in a cylinder and submitted to a constant force (weight) is considered. The paper importantly supplements a previously published paper: First, the stability of ideal gases is established. Second, we show that when walls separate the cylinder into parts and are later removed, the entropy is unaffected. We obtain full agreement with Landsberg’s and others’ (1994) classical thermodynamic result for the entropy of a column of gas submitted to gravity.
Reference Key
philippe2013entropya Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Fabrice Philippe;Jacques Arnaud;Laurent Chusseau
Journal European journal of medicinal chemistry
Year 2013
DOI
10.3390/e15093379
URL
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