Liquid-Film Assisted Mechanism of Reactive Flash Sintering in Oxide Systems.

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2019
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Abstract
Reactive flash sintering in oxide systems is analyzed assuming the formation of a liquid film at the particle contacts at the flash onset temperature. Formation of intermediate phases, as well as phase assemblage, are predicted upon optimal conditions of the electric field and current density. In single-phase impure oxides, the solidus and the solubility limit determine the flash onset temperature. In reacting binary systems, the composition of the liquidus determines primarily the reaction products during the cooling. In multicomponent systems, the oxide with the lowest flash temperature forms the interfacial liquid film, and the solid phase assemblage follows the equilibrium phase diagram. Examples from literature are consistent with reactive flash sintering and flash sintering assisted by a transient liquid film.
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chaim2019liquidfilmmaterials Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Chaim, Rachman;Amouyal, Yaron;
Journal Materials (Basel, Switzerland)
Year 2019
DOI
E1494
URL
Keywords
mechanical properties zno nanoparticles (bio)polymer nanocomposites barrier properties packaging applications

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