the synthesis of nio/tio2 heterostructures and their valence band offset determination

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ID: 205335
2014
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Abstract
In this work, a heterojunction based on p-type NiO/n-type TiO2 nanostructures has been prepared on the fluorine doped tin oxide (FTO) glass substrate by hydrothermal method. Scanning electron microscopy (SEM) and X-Ray diffraction techniques were used for the morphological and crystalline arrays characterization. The X-ray photoelectron spectroscopy was employed to determine the valence-band offset (VBO) of the NiO/TiO2 heterojunction prepared on FTO glass substrate. The core levels of Ni 2p and Ti 2p were utilized to align the valence-band offset of p-type NiO/n-type TiO2 heterojunction. The valence band offset was found to be ∼0.41 eV and the conduction band was calculated about ∼0.91 eV. The ratio of conduction band offset and the valence-band offset was found to be 2.21.
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Authors Z. H. Ibupoto, M. A. Abbasi, X. Liu, M. S. AlSalhi, M. Willander
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Journal reproductive biology and endocrinology
Year 2014
DOI
10.1155/2014/928658
URL
http://dx.doi.org/10.1155/2014/928658
Keywords
Technology (General)

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