crystal structure of (η2,η2-cycloocta-1,5-diene)(η5-indenyl)cobalt(i)
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ID: 204245
2016
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Abstract
The title compound, [Co(C8H12)(C9H7)], was synthesized by the reaction of metallated 2-H-indene with CoCl(PPh3)3 and 1,5-cyclooctadiene in tetrahydrofuran/toluene. In the molecule, the CoI atom is coordinated by the two double bonds of the 1,5-cyclooctadiene ligand and η5-bonded to the indenyl ligand. The asymmetric unit contains two molecules of the CoI complex with very similar conformations. In the crystal, molecules are arranged into rows parallel to [100]. Apart from dispersion forces, there are no notable intermolecular interactions in the crystal.
| Reference Key |
jungk2016iucrdatacrystal
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|---|---|
| Authors | ;Phillip Jungk;Anke Spannenberg;Marko Hapke |
| Journal | lecture notes in civil engineering |
| Year | 2016 |
| DOI |
10.1107/S2414314616000274
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