synthesis and characterization of the complexes of pentane-2,4-dione with nickel(ii) and cobalt(iii): [ni(acac)2]·0.5ch3oh and [co(acac)2no3]·2h2o (acac = pentane-2,4-dione)

Clicks: 239
ID: 202467
2004
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Abstract
Two mononuclear complexes, [Ni(acac)2]·0.5CH3OH (1) and[Co(acac)2NO3]·2H2O (2) (acac = pentane-2,4-dione), have been synthesized andcharacterized by single crystal X-ray analysis. Complex 1 crystallizes in the monoclinicspace group P21/c with a = 9.295(4), b = 11.450(5), c = 12.974(6) å, V = 1379.1(11) å3,β = 92.854(7), and Z = 4. Complex 2 crystallizes in the triclinic space group P(-1) with a= 8.153(9), b = 9.925(11), c = 10.355(12), V = 746.3(15) å3, α = 70.530(16), β =71.154(15), γ = 80.698(16) and Z = 2. Complex 1 has a one-dimensional chain-likestructure, which is extended by weak hydrogen contacts, while complex 2 shows a three–dimensional network structure.
Reference Key
tan2004moleculessynthesis Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Min-Yu Tan;Zhong-Lu You;Hai-Liang Zhu;Yang Qu
Journal Journal of ethnopharmacology
Year 2004
DOI
10.3390/91100949
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