investigations of the g factors and local structure for orthorhombic cu2+(1) site in fresh prba2cu3o6+x powders

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ID: 201752
2012
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Abstract
The electron paramagnetic resonance (EPR) g factors gx, gy and gz of the orthorhombic Cu2+(1) site in fresh PrBa2Cu3O6+x powders are theoretically investigated using the perturbation formulas of the g factors for a 3d9 ion under orthorhombically elongated octahedra. The local orthorhombic distortion around the Cu2+(1) site due to the Jahn-Teller effect is described by the orthorhombic field parameters from the superposition model. The [CuO6]10- complex is found to experience an axial elongation of about 0.04 Å along c axis and the relative bond length variation of about 0.09 Å along a and b axes of the Jahn-Teller nature. The theoretical results of the g factors based on the above local structure are in reasonable agreement with the experimental data.
Reference Key
song2012condensedinvestigations Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors B.T. Song, S.Y. Wu, M.Q.Kuang, X.F. Hu
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Journal conference on human factors in computing systems - proceedings
Year 2012
DOI
DOI not found
URL
http://dx.doi.org/10.5488/CMP.15.33701
Keywords Keywords not found

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