10-[1,1-dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10h-phenothiazine
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ID: 200653
2018
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Abstract
The title compound, C19H17Cl2NSSi, is an enamine derivative, in which the N atom adopts a shallow trigonal–pyramidal geometry [displacement from the plane of its attached C atoms = 0.1383 (18) Å]. The dihedral angle between the plane through the three amino carbon atoms and the vinyl group is 89.47 (7)°. The phenothiazine unit has a butterfly structure and the central six-membered ring adopts a boat conformation. The fold angle between the benzene rings is 28.52 (7)°. The crystal structure features weak Csp3—H...Cl hydrogen bonds, H...S contacts and π–π stacking interactions between phenothiazine units.
| Reference Key |
umezono2018iucrdata10-[1,1-dichloro-4-(trimethylsilyl)but-1-en-3-yn-2-yl]-10h-phenothiazine
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|---|---|
| Authors | ;Satoru Umezono;Tsunehisa Okuno |
| Journal | lecture notes in civil engineering |
| Year | 2018 |
| DOI |
10.1107/S2414314618002328
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| URL | |
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