4-methoxybenzylammonium nitrate

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ID: 200481
2017
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Abstract
In the title salt, C8H12NO+·NO3−, the 4-methoxybenzylammonium cation lies in the mirror plane m of space group Pnma and is thus planar by symmetry. The nitrate anion is also planar by symmetry, with an N...;O group in the mirror plane and one O atom in a general position. The dihedral angle between the benzene ring and the planar nitrate anion is constrained to be exactly 90°, because of the relative special positions for both ions. In the crystal, the cations are connected to the anions by C—H...O, C—H...N, N—H...N and N—H...O hydrogen bonds. Further, the crystal structure also features two C—H...π interactions involving the benzene ring of the cation, forming a three-dimensional network.
Reference Key
umarani2017iucrdata4-methoxybenzylammonium Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;P. Umarani;A. Thiruvalluvar;C. Ramachandra Raja
Journal lecture notes in civil engineering
Year 2017
DOI
10.1107/S2414314617011142
URL
http://scripts.iucr.org/cgi-bin/paper?S2414314617011142
Keywords
crystal structure hydrogen bond salt

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