rearrangements of cycloalkenyl aryl ethers

Clicks: 160
ID: 197849
2016
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Abstract
Rearrangement reactions of cycloalkenyl phenol and naphthyl ethers and the acid-catalyzed cyclization of the resulting product were investigated. Claisen rearrangement afforded 2-substituted phenol and naphthol derivatives. Combined Claisen and Cope rearrangement resulted in the formation of 4-substituted phenol and naphthol derivatives. In the case of cycloocthylphenyl ether the consecutive Claisen and Cope rearrangements were followed by an alkyl migration. The mechanism of this novel rearrangement reaction is also discussed.
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trincsi2016moleculesrearrangements Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Mercedesz Törincsi;Melinda Nagy;Tamás Bihari;András Stirling;Pál Kolonits;Lajos Novak
Journal Journal of ethnopharmacology
Year 2016
DOI
10.3390/molecules21040503
URL
Keywords Keywords not found

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