structural characteristics and non-linear optical behaviour of a 2-hydroxynicotinate-containing zinc-based metal-organic framework

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ID: 194730
2015
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Abstract
Materials with non-linear optical (NLO) properties play an important role in the construction of electronic devices for optical communications, optical data processing and data storage. With this aim in mind, a Zn(II)-based metal-organic framework {[Zn2(nica)2(bpy)1.5(H2O)]×0.5(bpy)×3H2O}n (1), was synthesized using 4,4ʹ-bipyridine (bpy) and a potentially bidentate ligand, 2-hydroxynicotinic acid (H2nica) with a salicylate binding moiety. A single-crystal X-ray diffraction analysis revealed that compound 1 crystallized in the orthorhombic space group Fdd2 and was composed of a three dimensional porous framework. Since Fdd2 belonged to a class of non-centrosymmetric space groups, we therefore investigated the non-linear optical behaviour of compound 1. Photoluminescence studies revealed that compound 1 exhibited a blue light emission with a maxima at 457 nm.
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mendiratta2015moleculesstructural Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Shruti Mendiratta, Cheng-Hua Lee, Sih-Ying Lee, Ya-Chuan Kao, Bor-Chen Chang, Yih-Hsing Lo, Kuang-Lieh Lu
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Journal Journal of ethnopharmacology
Year 2015
DOI
10.3390/molecules20058941
URL
http://www.mdpi.com/1420-3049/20/5/8941
Keywords
4 emission metal-organic framework

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