relative entropy, interaction energy and the nature of dissipation
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ID: 188579
2014
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Abstract
Many thermodynamic relations involve inequalities, with equality if a process does not involve dissipation. In this article we provide equalities in which the dissipative contribution is shown to involve the relative entropy (a.k.a. Kullback-Leibler divergence). The processes considered are general time evolutions both in classical and quantum mechanics, and the initial state is sometimes thermal, sometimes partially so. By calculating a transport coefficient we show that indeed—at least in this case—the source of dissipation in that coefficient is the relative entropy.
| Reference Key |
gaveau2014entropyrelative
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|---|---|
| Authors | ;Bernard Gaveau;Léo Granger;Michel Moreau;Lawrence S. Schulman |
| Journal | European journal of medicinal chemistry |
| Year | 2014 |
| DOI |
10.3390/e16063173
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| URL | |
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