The effect of homocysteine and homocystine protonation on double-layer parameters at the electrode/chlorates(VII) interface

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ID: 188228
2017
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Abstract
In this study, a comparison of the properties of homocysteine and homocystine adsorption at mercury/chlorate(VII) interface was done. The adsorption of homocysteine and homocystine is in fact the adsorption of mercury(II) cysteine thiolate and mercury(I) cysteine thiolate. The differences in the capacity curves result probably from the formation of mercurous thiolate at the mercury surface. It seems that the changes in E z and γ z values accompanying the change in the amino acid protonation in the basic electrolyte solution, confirm the altered arrangement of the cysteine mercury thiolates on the electrode surface.
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Authors Nosal-Wiercińska, Agnieszka;Wiśniewska, Małgorzata;Grochowski, Mariusz;Kaliszczak, Waldemar;Skrzypek, Sławomira;Brycht, Mariola;Guziejewski, Dariusz;Franus, Wojciech;
Journal adsorption science & technology
Year 2017
DOI
DOI not found
URL
https://doi.org/10.1177/0263617416689271
Keywords
chemistry Medicine Chemical technology Biotechnology Technology Science physical and theoretical chemistry chemical engineering

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