new guanidine-pyridine copper complexes and their application in atrp

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ID: 185235
2014
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Abstract
The guanidine hybrid ligands, (tetramethylguanidine)methylenepyridine (TMGpy) and (dimethylethyleneguanidine)methylenepyridine (DMEGpy), were proven to be able to stabilize copper complexes active in the solvent-free polymerization of styrene at 110 °C using 1-phenylethylbromide as the initiator. The polymerization proceeded after first-order kinetics, and polystyrenes with polydispersities around 1.2 could be obtained. Using the ligand, DMEGpy, three new copper guanidine-pyridine complexes could be synthesized and structurally characterized. Their structural characteristics are discussed.
Reference Key
hoffmann2014polymersnew Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Alexander Hoffmann;Olga Bienemann;Ines dos Santos Vieira;Sonja Herres-Pawlis
Journal Journal of Fluorescence
Year 2014
DOI
10.3390/polym6040995
URL
http://www.mdpi.com/2073-4360/6/4/995
Keywords
polymerization

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