kinetics and mechanism of oxidation of diethanolamine and triethanolamine by potassium ferrate
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ID: 182375
2011
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Abstract
The kinetics of oxidation of diethanolamine and triethanolamine by potassium ferrate(VI) in alkaline liquids at a constant ionic strength has been studied spectrophotometrically in the temperature range of 278.2 K-293.2 K. The reaction shows first order dependence on potassium ferrate(VI), first order dependence on each reductant, The observed rate constant (kobs) decreases with the increase in [OH-], the reaction is negative fraction order with respect to [OH-]. A plausible mechanism is proposed and the rate equations derived from the mechanism can explain all the experimental results. The rate constants of the rate-determining step and the thermodynamic activation parameters are calculated.
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jinhuan2011e-journalkinetics
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|---|---|
| Authors | ;Shan Jinhuan;Zhang Jiying |
| Journal | Journal of pharmaceutical and biomedical analysis |
| Year | 2011 |
| DOI |
10.1155/2011/267894
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