synthesis of ethylenic and acetylenic triorganotins with bulky organic ligands
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2000
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Abstract
The syntheses of trineophyl- (1a) and tri-(-)-menthylstannyl phenylacetylene (1b) as well as that of (E)-1-trineophylestannyl-2-phenylethene (2) and (E)-1-trineophylstannyl-1,2-diphenylethene (3) are described. The hydrostannation of 1a with an excess of trimethyltin hydride led to 1,1,1-tris(trimethyltin)-2-phenylethane (4) and/or 1,1-bis(trimethyltin)-2-phenylethene (5) depending on the reaction conditions.
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dodero2000moleculessynthesis
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| Authors | ;V. Dodero;L. C. Koll;J. C. Podestá |
| Journal | Journal of ethnopharmacology |
| Year | 2000 |
| DOI |
10.3390/50300439
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