synthesis of ethylenic and acetylenic triorganotins with bulky organic ligands

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ID: 179554
2000
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Abstract
The syntheses of trineophyl- (1a) and tri-(-)-menthylstannyl phenylacetylene (1b) as well as that of (E)-1-trineophylestannyl-2-phenylethene (2) and (E)-1-trineophylstannyl-1,2-diphenylethene (3) are described. The hydrostannation of 1a with an excess of trimethyltin hydride led to 1,1,1-tris(trimethyltin)-2-phenylethane (4) and/or 1,1-bis(trimethyltin)-2-phenylethene (5) depending on the reaction conditions.
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dodero2000moleculessynthesis Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors V. Dodero, L. C. Koll, J. C. Podestá
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Journal Journal of ethnopharmacology
Year 2000
DOI
10.3390/50300439
URL
http://www.mdpi.com/1420-3049/5/3/439/
Keywords
stereoselectivity addition substitutionorganic chemistry

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