time and temperature dependence of cds nanoparticles grown in a polystyrene matrix
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ID: 177302
2012
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Abstract
Luminescent CdS nanocrystals embedded in a polystyrene matrix were successfully prepared. The in situ growth of CdS QDs was realized by thermal treatment of Cd bis(thiolate)/polymer foil at different times and temperatures (240°C and 300°C) of annealing, in order to evaluate their influence on the quantum dots growth process. As a general trend, the increasing of time and temperature of annealing induces a rise of the CdS nanocrystals size into the polymeric matrix. The size distribution, morphology, and structure of the CdS nanoparticles were analysed with HRTEM and XRD experiments. UV-Vis and PL data are strongly size-dependent and were used to investigate the particles' growth process, too. The CdS nanoparticles behavior in solution indicated a general trend of QDs to aggregation. This predisposition was clearly displayed by DLS measurements.
| Reference Key |
antolini2012journaltime
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| Authors | ;F. Antolini;E. Burresi;L. Stroea;V. Morandi;L. Ortolani;G. Accorsi;M. Blosi |
| Journal | reproductive biology and endocrinology |
| Year | 2012 |
| DOI |
10.1155/2012/815696
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| URL | |
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