copper 5,10,15,20-tetrakis-(3,4-dibenzyloxyphenyl)porphyrin
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ID: 170452
2017
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Abstract
The copper complex of 5,10,15,20-tetrakis-(3,4-dibenzyloxyphenyl)porphyrin (CuTDBOPP) was synthesized and characterized with electronic absorption spectroscopy and ESI high-resolution spectrometry. In the electronic spectrum, there was a shift in the Soret band from 424 nm to 420 nm that indicated that the insertion of the metal ion was successful. Additionally, the number of Q bands decreased from four peaks to a single peak at 541 nm. The molar absorptivity of the Soret and Q band are 3.4 × 105 cm−1·M−1 and 1.8 × 105 cm−1·M−1, respectively. The ESI HRMS was in excellent agreement with simulated isotopic distribution spectra. CuTDBOPP was incorporated into a series of Gratzel cells where the open current voltage was recorded.
| Reference Key |
mathews2017molbankcopper
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|---|---|
| Authors | ;L. Dalila Mathews;Cynthia P. Tidwell;Prakash Bharara;Glenn Stephens;Ting Yu Su;Alexia Carter |
| Journal | journal of chemical sciences |
| Year | 2017 |
| DOI |
10.3390/M931
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