thiocyanate ion-selective pvc membrane electrode
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ID: 170232
2010
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Abstract
A potentiometric selective sensor based on trinuclear chromium(III) complex as a novel ionophore for the thiocyanateselective electrode is reported. The sensor displays a near Nernstian slope of 57 ± 2 mV per decade, over a wide pH range 3 - 11. The working concentration range of the electrode is 1.10-5 – 1.10-1 mol/l with a detection limit of 5.10-6 mol/l. The sensor has a
response time of 20 s and can be used for at least 6 months without any considerable fluctuation of the potential. The selectivity coefficients determined at using the fixed interference method
indicate a good discriminating ability towards other anions. The prepared sensor was applied as an indicator electrode in the titration of thiocyanate with Ag+.
| Reference Key |
revenco2010chemistrythiocyanate
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|---|---|
| Authors | ;Mihail Revenco;Mariana Martin;Waell Abu Dayyih |
| Journal | advances in fuzzy systems |
| Year | 2010 |
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