direct oxidation of benzene to phenol in liquid phase by h2o2 over vanadium catalyst supported on highly ordered nanoporous silica
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2011
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Abstract
Vanadium supported on highly ordered nanoporous silica (VOx-LUS-1) was synthesized and characterized by XRD, Nitrogen adsorption‑desorption isotherms and UV-visible spectrophotometer. Direct oxidation of benzene to phenol in liquid phase by H2O2 peroxide were examined by using various solvents (methanol, acetone, acetic acid, acetonitryl). The maximum yield (25%) and selectivity (73%) of the phenol produced were obtained in the presence of acetic acid. The catalyst can be reused for several times without any appreciable loss of activity.
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| Authors | ;A. R. Badiei;J. Gholami;G. Mohammadi Ziarani;A. R. Abbasi |
| Journal | process safety progress |
| Year | 2011 |
| DOI |
10.7508/jns.2011.01.010
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