catena-poly[[diaquabis[1,4-bis(pyridin-4-yl)buta-1,3-diyne-κn]iron(ii)]-μ-cyanido-κ2n:c-[dicyanido-κ2c-platinum(ii)]-μ-cyanido-κ2c:n]
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ID: 163133
2017
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Abstract
The molecular structure of the title compound, [FePt(CN)4(C14H8N2)2(H2O)2]n, consists of one-dimensional polymeric [–Fe–NC–Pt(CN)2–CN–]∞ chains. Two water molecules and two monodentate 1,4-bis(pyridin-4-yl)buta-1,3-diyne (bpb) ligand molecules complete the octahedral coordination sphere of the FeII atoms. The Fe—N(py) bond length (py is pyridine) is 2.2700 (15) Å, Fe—N(cyanide) is 2.1185 (16) Å and the Fe—O distance is 2.1275 (14) Å. The water molecules are hydrogen bonded to either bpb ligands or cyanide groups of the planar [Pt(CN)4]2− anion of adjacent polymeric chains. These O—H...N hydrogen bonds, in conjunction with offset and tilted π–π stacking interactions between bpb ligands and cyanide groups, extend the one-dimensional chains into a three-dimensional assembly.
| Reference Key |
pieiro-lpez2017iucrdatacatena-poly[[diaquabis[1,4-bis(pyridin-4-yl)buta-1,3-diyne-n]iron(ii)]--cyanido-2n:c-[dicyanido-2c-platinum(ii)]--cyanido-2c:n]
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|---|---|
| Authors | ;Lucia Piñeiro-López;Francisco Javier Valverde-Muñoz;Maksym Seredyuk;Kateryna Znovjyak |
| Journal | lecture notes in civil engineering |
| Year | 2017 |
| DOI |
10.1107/S2414314617014134
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| URL | |
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