free volume and gas permeation in anthracene maleimide-based polymers of intrinsic microporosity

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ID: 155396
2015
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Abstract
High free-volume copolymers were prepared via polycondensation with 2,3,5,6,-tetrafluoroterephthalonitrile (TFTPN) in which a portion of the 3,3,3',3'-tetramethyl-1,1'-spirobisindane (TTSBI) of PIM-1 was replaced with dibutyl anthracene maleimide (4bIII). An investigation of free volume using positron annihilation lifetime spectroscopy (PALS), and gas permeation measurements was carried out for the thin film composite copolymer membranes and compared to PIM-1. The average free volume hole size and the gas permeance of the copolymer membranes increased with decreasing TTSBI content in the copolymer.
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khan2015membranesfree Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Muntazim Munir Khan;Volkan Filiz;Thomas Emmler;Volker Abetz;Toenjes Koschine;Klaus Rätzke;Franz Faupel;Werner Egger;Luca Ravelli
Journal advances in pharmacological sciences
Year 2015
DOI
10.3390/membranes5020214
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