coordination polymers of n, nʼ-di-(8-hydroxyquinolinolyl- 5-methyl)-n, n-diethyl-1,3-propane diamine (qepd)
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ID: 154307
2010
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Abstract
Coordination polymers containing a novel bis(oxine) bidentate ligand, namely N,Nʼ-di(8-hydroxyquinolinolyl-5-methyl)-N,Nʼ-diethyl-1,3-propane diamine (QEPD) have been prepared with the metal ions Zn(II), Cu(II), Ni(II), Co(II) and Mn(II). The novel bis-(bidentate) ligand was synthesized by condensation of 5-chloromethyl-8-hydroxyquinoline hydrochloride with N,Nʼ-diethyl-1,2- propane diamine in the presence of a base catalyses. All of these coordination polymers and the parent ligand were characterized by elemental analyses, IR spectral and diffuse reflectance spectral studies. The thermal stability and number- average molecular weights (Mn¯) of all of the coordination polymers were determined by thermogravimetric analyses and non-aqueous conductometric titrations, respectively. In addition, all of the coordination polymers have been characterized by their magnetic susceptibilities.
| Reference Key |
patel2010e-journalcoordination
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|---|---|
| Authors | ;Asha D. Patel;Rignesh S. Patel;Ganpat R. Patel |
| Journal | Journal of pharmaceutical and biomedical analysis |
| Year | 2010 |
| DOI |
10.1155/2010/609494
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