A General Proline Catalyzed Synthesis of 4,5-Disubstituted N-Sulfonyl-1,2,3-Triazoles from 1,3-Dicarbonyl Compounds and Sulfonyl Azide.

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ID: 14833
2019
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Abstract
An efficient proline catalyzed synthesis of 4,5-disubstituted-N-sulfonyl-1,2,3-triazoles have been accomplished from 1,3-dicarbonyl compounds and sulfonyl azides. The developed reaction is suitable for various symmetrical and unsymmetrical 1,3-dicarbonyl compounds, tolerates various functional groups and affords 4,5-disubstituted-N-sulfonyl-1,2,3-triazoles in good yield with excellent regioselectivity. Rhodium catalyzed denitrogenative functionalization of 4,5-disubstituted-N-sulfonyl-1,2,3-triazoles further demonstrates their utility in organic synthesis.
Reference Key
rajasekar2019achemistry Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Rajasekar, Shanmugam;Anbarasan, Pazhamalai;
Journal Chemistry, an Asian journal
Year 2019
DOI
10.1002/asia.201901015
URL
Keywords Keywords not found

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