Ru-Catalyzed Chemo- and Enantioselective Hydrogenation of β-Diketones Assisted by the Neighboring Heteroatoms.

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ID: 1470
2019
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Abstract
A highly chemo- and enantioselective hydrogenation of β-diketones was achieved by using [Ru(benzene)( S)-SunPhosCl]Cl for consistency in THF. The neighboring heteroatoms played important roles in guaranteeing the reactivity and controlling the chemoselectivity. These results suggested a potential approach for the clean and facile synthesis of functionalized chiral β-hydroxy ketones, which could otherwise be prepared through much less step-economic transformations.
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li2019ru-catalyzed Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Li, Wanfang;Lu, Bin;Xie, Xiaomin;Zhang, Zhaoguo;
Journal Organic letters
Year 2019
DOI
10.1021/acs.orglett.9b01829
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