Stereodivergent Access to Enantioenriched Epoxy Alcohols with Three Stereogenic Centers via Ruthenium-Catalyzed Transfer Hydrogenation.

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ID: 1469
2019
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Abstract
The resolution technique of stereodivergent reaction on racemic mixtures (stereodivergent RRM) was employed for the first time in ruthenium complex catalyzed transfer hydrogenation of racemic epoxy ketones, providing a new and very simple method that allows access to enantioenriched epoxy alcohols with three stereogenic centers in a one-step fashion. The protocol features simple reaction conditions, practical operation, ability to scale up, and broad group tolerance.
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zhao2019stereodivergent Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Zhao, Zhifei;Bagdi, Prasanta Ray;Yang, Shuang;Liu, Jinggong;Xu, Weici;Fang, Xinqiang;
Journal Organic letters
Year 2019
DOI
10.1021/acs.orglett.9b01789
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