Development of modified mesoporous carbon (CMK-3) for improved adsorption of bisphenol-A.
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2019
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Abstract
The adsorption of bisphenol-A (BPA) on ordered mesoporous carbon (CMK-3) and modified CMK-3 (MCMK-3) for decontamination of aqueous medium was investigated. The CMK-3 and MCMK-3 materials had uniform pore sizes of 3.60 and 3.70 nm and high Brunauer-Emmett-Teller (BET) surface areas of 751 and 564 m g, respectively. The maximum adsorption capacities of CMK-3 and MCMK-3 were 178.57 (0.24 mg m) and 238.01 (0.42 mg m) mg g, respectively at 298 K (pH 6.4). The difference in the adsorption capacities is attributed to the specific surface area and hydrophobicity of the adsorbents. The adsorption of BPA on CMK-3 and MCMK-3 may be influenced by π-π bonding and hydrophobic and electrostatic interactions, and the excellent adsorption capacity of MCMK-3 is attributed to its unique sp2-hybridized single-atom-layer structure. The kinetics and isotherm data were described by the pseudo-second order kinetic model and the Langmuir isotherm, respectively. This difference in the adsorption kinetics of CMK-3 and MCMK-3 is caused by the increase in the pore diameter of the latter. Further, CMK-3 and MCMK-3, with an open geometry consisting of interlinked nanorods, allow for faster intraparticle diffusion. Overall, CMK-3 and MCMK-3 could be promising adsorbents for the removal of chemicals containing benzene rings from wastewater.
| Reference Key |
jeong2019developmentchemosphere
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|---|---|
| Authors | Jeong, Yunjae;Cui, Mingcan;Choi, Jongbok;Lee, Yonghyeon;Kim, Jeonggwan;Son, Younggyu;Khim, Jeehyeong; |
| Journal | Chemosphere |
| Year | 2019 |
| DOI |
S0045-6535(19)31783-7
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| URL | |
| Keywords | Keywords not found |
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