ionic liquids: the synergistic catalytic effect in the synthesis of cyclic carbonates

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ID: 138642
2013
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Abstract
This review presents the synergistic effect in the catalytic system of ionic liquids (ILs) for the synthesis of cyclic carbonate from carbon dioxide and epoxide. The emphasis of this review is on three aspects: the catalytic system of metal-based ionic liquids, the catalytic system of hydrogen bond-promoted ionic liquids and supported ionic liquids. Metal and ionic liquids show a synergistic effect on the cycloaddition reactions of epoxides. The cations and anions of ionic liquids show a synergistic effect on the cycloaddition reactions. The functional groups in cations or supports combined with the anions have a synergistic effect on the cycloaddition reactions. Synergistic catalytic effects of ILs play an important role of promoting the cycloaddition reactions of epoxides. The design of catalytic system of ionic liquids will be possible if the synergistic effect on a molecular level is understood.
Reference Key
ng2013catalystsionic Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Flora T.T. Ng;Jinquan Wang;Jian Sun;Weiguo Cheng;Qian Su
Journal journal of essential oil research
Year 2013
DOI
10.3390/catal3040878
URL
http://www.mdpi.com/2073-4344/3/4/878
Keywords
ionic liquid synergistic effect cyclic carbonates carbon dioxidechemical technologychemistry

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